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It does but unless you have a leaking tire or are using it all the time, there's not much air exchange. For most of us the tires stay in highway mode 98% of the time.

Not going to happen in a mostly sealed tire. The air inside the tire can only hold so much water vapor and once it's saturated to it's dew point evaporation stops. There is some exchange over time as you inflate and deflate but it's not going to be much.

You mix it with water - 25% water to 75% EG is enough.... Freezing point is about negative 50 degrees F or lower.

Immediately after I added it I did get some that wanted to come back out the valve stem but once it went down into the tire proper past the bead locks I haven't had any signs of it. Not sure exactly how that would be possible. I have run my truck through a full cycle from sand to highway with it...

I found that a half gallon of anti-freeze in each tire worked well for me. I tried one quart (32oz) and that wasn't sufficient. I don't have any issue with the CTIS once the anti-freeze worked it's way past the bead lock. I had my rims powder coated and mounted the new tires myself. The balance...